Chemistry · Class XII Sc · DOWNLOAD pdf

p-Block elkements(Gr 16,17,18) Reason based question and answer

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p Block reasoning new  word

p Block reasoning new pdf

SN PROPERTY/QUESTION REASON
1 Sulphur has greater catenation than oxygen S-S bond is stronger bond than O-O
2 Supersonic jet planes are responsible for ozone depletion Emission of NO. NO+O3=NO2+O2
3 SF4 is easily hydrolysed than SF6 SF6 is exceptionally stable to octahedral symmetry.
4 H2O is more polar than H2S Oxygen is more electronegative.
5 O2 is paramagnetic Presence of two unpaired electron in antibonding MO
6 Oxygen do not show +4 or +6 O.S Due to absence of d-orbital in oxygen
7 Ozone acts as oxidizing agent Due to liberation of nascent oxygen.
8 Sulphur is solid , oxygen is a gas Pπ- Pπ bonding in oxygen. Sulphur shows catenation
9 SO2 is an air pollutants SO2+H2O=H2SO4 Which is corrosive and poisonous.
10 In  contact process for the preparation of H2SO4, SO3 is absorbed in H2SO4. SO3 forms acid fog when absorbed in H2O.
11 Ka2 is less than Ka1 for H2SO4 in H2O HSO4- has less tendency to donate proton as compared to H2SO4
12 Oxygen forms hydrogen bond but chlorine does not Size of oxygen is small in comparison to chlorine
13 HClO4 is stronger acid than HClO3 Higher oxidation state of non metal, highernon metallic character, more is acidic strength.
14 Halogens are strong oxidizing agent Halogens readily accepts electron
15 ClF3 has T- shaped structure Sp3d hybridization
16 Bond dissociation energy of F2 is less than Cl2 Due to small size of F, interelectronic repulsion is larger than Cl
17 Covalent fluoride is more inert than other covalent halide Stronger bond with fluorine.

 

18 ClF3 exist but FCl3 does not Size of fluorine is too small to hold three bulky chlorine
19 ICl is more reactive than I2 I-Cl bond is weaker bond than I2
20 Halogens are coloured Absorption  of light in visible range
21 Structure of xenon fluoride can not be explained by VBT Xenon has fulfilled orbital.
21 Noble gases have comparatively large atomic size. Vander wall radii is larger than metallic and covalent radii.
22 Noble gas form compounds with oxygen and fluorine oxygen and fluorine are more electronegative
23 Helium is used in diving apparatus He is less soluble in blood